Abstract
The Front Cover shows an “O2 grasshopper” captured by two “Copper scorpions” using their strong claws and tails (outer-sphere hydrogen bonds). As the key intermediate in the biological oxygenation, the trans-1,2-peroxodicopper adduct was mimicked by a variety of molecular copper complexes. The structure-activity models of hydrogen-bond-assisted tetradentate copper(I) chloride and trans-1,2-peroxodicopper complexes were established, and fundamental insights on the mimics were obtained. More information can be found in the Full Paper by G. Liang and co-workers.
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