Abstract

The cover picture shows the crystal packing of a palladium complex of a carbazole-based chalcogenaisophlorin. Metalation planarizes the structure, inducing weak near infrared (NIR) absorption typical for antiaromatic porphyrinoids in solution. The sulfur- and selenium-based complexes formed trimeric and dimeric stacked layered structures, respectively, and showed relatively strong NIR absorption in the solid state. More details can be found in the Communication by C. Maeda et al. on page 1368 in Issue 12, 2017 (DOI: 10.1002/cplu.201700430).

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