Abstract

An unprecedented catalytic protocol for the asymmetric decarbonylative transformation: The cover art depicts how the asymmetric reaction of the Ir/S−Me-BIPAM complex takes precedence over the decarbonylation. The picture of the balance shows that the competing decarbonylation side reaction will not happen, as well as highlighting the asymmetry. More information can be found in the Research Article by T. Shirai et al. (DOI: 10.1002/chem.202104347).

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