Abstract
Analysis of some relevant aspects of crystallisation of linear, stereoregular polymers is carried out. Specifically, we consider (1) the pre-crystallisation state of polyethylene in solution according to the bundle theory, (2) the difficulty of isotactic polystyrene in undergoing crystallisation and (3) the prediction power of the intra-molecular lowest-energy principle as applied specifically to iso- and syndiotactic polypropylene.
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