Abstract

The first attempt to represent the Periodic system graphically was the Telluric Helix (Vis Tellurique) presented in 1862 by Alexandre-Emile Béguyer de Chancourtois, in which the sequence of elements was wound round a cylinder. This has hardly been attempted since, because the intervals between periodic returns vary in length from 2 to 32 elements, but Charles Janet presented a model wound round four nested cylinders. The rows in Janet’s table are defined by a constant sum of the first two quantum numbers, n and l, so that they end with the s-block, headed by hydrogen and helium. By combining Janet’s table, Edward Mazurs’ version, in which each row represents an electron shell and Valery Tsimmerman’s use of a half square for each element, I have produced a representation that can be printed out and wound round to make a cylinder with manageable dimensions. In the unwound version, I have placed the s-block in the middle, to emphasise its pivotal nature, since it both ends each (n + ℓ) row and contributes electrons to the valence of elements in the next (n + ℓ) row; it thus does not necessarily belong either on the left or the right side of a table. The downward arrows that link subshells within each (n + ℓ) series graphically illustrate the Janet Effect (or Madelung Rule). To acknowledge my debt to Chancourtois, Janet, Mazurs and Tsimmerman, I call my design the ‘Telluric Remix’.

Highlights

  • A helix with constant diameter could not work for the periodic system without gaps in all except the longest sequences, because the intervals between periodic returns vary in length from 2 to 32 elements

  • Subsequent efforts to represent the periodic system as a helix with cylindrical outline recognised the need to vary the size of the coils; a successful attempt to draw this in two dimensions was that of Georg Schaltenbrand (1920)

  • A cone would have been a possible alternative to a cylinder, but the projection of a cone on to its base is a spiral, and spirals have been popular since the version produced by Baumhauer (1969)

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Summary

History of helical versions

The Telluric Helix (La Vis Tellurique) was the first graphic representation of the periodic system of the elements, conceived as a spiral wound round a cylinder. It was designed by Alexandre-Émile Béguyer de Chancourtois (1862), a French mineralogist. A helix with constant diameter could not work for the periodic system without gaps in all except the longest sequences, because the intervals between periodic returns vary in length from 2 to 32 elements Chancourtois divided his cylinder into 32 vertical columns, but this was the effect of halving the circle five times; for the groups of elements to line up, there would have been big gaps. Tables have the advantage of utility and convenience, especially for eyes used to pages in the Roman, Cyrillic or similar alphabets

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My telluric remix
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