Abstract
The research activities of our group are demonstrated by examples in the following fields: (i) TADDOL auxiliary system (combinatorial synthesis, a chiral hydroperoxide, immobilization on controlled-pore glass silica gel); (ii) a geminally diphenyl-substituted 4-isopropyl-1,3-oxazolidinone as a superior Evans-type auxiliary (for enantioselective enolate alkylation, aldol addition, Michael addition, and Diels-Alder reactions); (iii) enantioselective reactivity umpolung (with a lithiated methylthiomethyl derivative of an oxazolidinone), and (iv) chemical and biological investigations of γ-peptides (folding to helices and turns, stability against peptidases). The impact of biology on the projects of a synthetic organic group is discussed.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
