Abstract
AbstractA practical synthesis of axially chiral biaryls via chirality transfer from peripheral stereogenic carbon centers is reported. In contrast to the traditional aromatization process of a non‐aromatic structure withipsostereogenic centers, this method is based on a Pd‐catalyzed carbon‐carbon bond cleavage/ring‐opening reaction of optically active 8H‐indenothiophen‐8‐ols with an achiral ligand, enabling synthesis of highly functionalized 3‐arylthiophene atropisomers in high enantioselectivity.magnified image
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