Abstract
Continuous-flow microreactors offer major advantages for photochemical applications. This mini-review summarizes the technological development of microflow devices in the Applied and Green Photochemistry Group at James Cook University, and its associates, from fixed microchips for microscale synthesis to flexible multicapillary systems for parallel photochemistry. Whereas the enclosed microchip offered high space–time-yields, the open capillary-type reactor showed a greater potential for further modifications. Consequently, a 10-microcapillary reactor was constructed and used successfully for process optimization, reproducibility studies, scale-up, and library synthesis. To demonstrate the superiority of microflow photochemistry over conventional batch processes, the reactors were systematically evaluated using alcohol additions to furanones as model reactions. In all cases, the microreactor systems furnished faster conversions, improved product qualities, and higher yields. UVC-induced [2+2] cycloadditions of furanone with alkenes were exemplarily examined in a capillary reactor, thus proving the broad applicability of this reactor type.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
