From interface effect to bulk effect: Probing the capacitive coupling enhancement mechanism to achieve high performance DC droplet-based nanogenerator

Abstract

The DC droplet-based nanogenerator (DNG) technology has opened up a new avenue for high-entropy water energy harvesting. However, the conventional DC DNG relies on the interface effect to generate a limited surface charge density, which severely restricts its electrical performance. Here, inspired by the MOS transistors, a novel total current DNG (TC-DNG) platform with back-gate modulation structure is developed, successfully realizing the transform from interface effect to bulk effect. By using the rationally patterned DNG as triboelectric probe, an intriguing capacitive coupling enhancement mechanism is discovered. With such a mechanism, the nanogenerator could employ both the capacitive coupling effect of the back-gate electrode and the self-exciting effect of droplet charge-shuttles to achieve a significantly enhanced performance in both charge transfer and voltage output. As a result, this TC-DNG provides a transferred charge of 30 nC per droplet and an output voltage of 800 V and is capable of illuminating 480 high-brightness LEDs without using any power management circuit. In addition, this TC-DNG could easily adapt to a wide range of application scenarios owing to the interchangeability of the back-gate material. This work could inspire further innovations in energy transfer mechanism and harvesting technology at the liquid-solid interface.