From Chlorella to Nestlike Framework Constructed with Doped Carbon Nanotubes: A Biomass-Derived, High-Performance, Bifunctional Oxygen Reduction/Evolution Catalyst.

Abstract

The development of effective bifunctional catalysts for the oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) is significant for energy conversion systems, such as Li-air batteries, fuel cells, and water splitting technologies. Herein, a Chlorella-derived catalyst with a nestlike framework, composed of bamboolike nanotubes that encapsulate cobalt nanoparticles, has been prepared through a facile pyrolysis process. It achieves perfect bifunctional catalysis both in ORR and OER on a single catalyst. For our optimal catalyst Co/M-Chlorella-900, its ORR half-wave potential is positively shifted by 40 mV compared to that of a commercial Pt/C catalyst, and the overpotential at 10 mA cm-2 for the OER is 23 mV lower than that of a commercial IrO2/C catalyst in an alkaline medium. This superior bifunctional catalytic performance is benefited from the simultaneous increase of pyridinic N sites for ORR and graphitic N sites for OER. In addition, N-doped carbon-encapsulated Co nanoparticles improve both ORR and OER performance by forming new active centers. The unique nestlike carbon nanotube framework not only afforded highly dense ORR and OER active sites but also promoted the electron and mass transfer. Our catalyst also displays notable durability during the ORR and OER, making it promising for use in ORR/OER-related energy conversion systems.