Abstract

MoS2-multi-walled-carbon-nanotube (MWCNT) hybrids containing two-dimensional MoS2 and one-dimensional MWCNTs were synthesized through a one-step hydrothermal reaction. X-ray-diffraction and transmission-electron-microscopy results demonstrated that MoS2 nanosheets were successfully synthesized, and uniformly anchored on the MWCNTs’ surfaces. Furthermore, the effects of the MoS2-MWCNT hybrids on the tribological performances of polyurethane composite coatings were investigated using a UMT-2MT tribo-tester. Friction and wear test results revealed that the friction coefficient and wear rate of a 3 wt% MoS2-MWCNT-1 filled polyurethane composite coating were reduced by 25.6% and 65.5%, respectively. The outstanding tribological performance of the MoS2-MWCNT-1 reinforced polyurethane composite coating was attributed to the excellent load-carrying capacity of the MWCNTs and good lubricant ability of MoS2. The surface morphologies of the worn surfaces and counterpart ball surfaces were investigated to reveal the wear mechanisms.

Highlights

  • In recent years, polymer matrix composites have emerged as attractive materials in the industrial community

  • The friction coefficient of the 3 wt% MoS2-MWCNT-1 reinforced polyurethane composite coating was reduced by 25.6%

  • The MoS2-MWCNT-1 reinforced polyurethane composite coating exhibited a lower and more stable friction coefficient than that of the pristine polyurethane composite coating during the sliding process. These results indicate that the MoS2-MWCNT-1 hybrid as a lubricant filler has a significant influence on the tribological performance of the polyurethane composite coating

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Summary

Introduction

Polymer matrix composites have emerged as attractive materials in the industrial community. Thermoplastic polyurethane composites have attracted a significant attention owing to their outstanding chemical resistance, toughness, adhesive and anti-wear properties [5−7]. Polyurethane exhibits these properties, there are challenges associated to friction and wear performance [8]. Two-dimensional (2D) nano-materials have attracted a significant attention owing to their unique lamellar structure and superior lubricant properties [16−23]. The results revealed that all fullerene-like MoS2 can effectively reduce the friction coefficient and wear volume. Hu et al [22] have synthesized

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