Abstract
This work focuses on the experimental study of the conductivity and the permittivity of ZnO–P2O5/Co (ZP/Co) composites as function of frequency in the range of 100–106 Hz at room temperature. The conductivity evolution shows a high percolating jump from low to high loaded ZP matrix with Co filler, indicating an insulator–semiconductor phase transition. Above the percolation threshold, the obtained conductivity is between 10−1 and 10° S/cm and is frequency independent. While, for low filler volume fraction, it is frequency dependent and it is about 10−8 S/cm at 100 Hz. Moreover, it should be noticed that around the percolation threshold, a significant value of dielectric constant about 105 was observed at room temperature and low frequency 100 Hz. Furthermore, the distribution of the relaxation processes was also investigated below the percolation threshold. Indeed, a relaxation peak about 106 rad/s in the curves of electric modulus M″(ω) was observed. It is successively described by Davidson–Cole model and an account of the interpretation of obtained results is given.
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More From: Journal of Materials Science: Materials in Electronics
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