Freezing of molecular rotation in a paramagnetic crystal studied by P31 NMR

Abstract

We present a detailed $^{31}\mathrm{P}$ nuclear magnetic resonance (NMR) study of the molecular rotation in the compound $[\mathrm{Cu}{(\mathrm{pz})}_{2}{(2\ensuremath{-}\mathrm{HOpy})}_{2}]{({\mathrm{PF}}_{6})}_{2}$, where $\mathrm{pz}={\mathrm{C}}_{4}{\mathrm{H}}_{4}{\mathrm{N}}_{2}$ and $2\ensuremath{-}\mathrm{HOpy}={\mathrm{C}}_{5}{\mathrm{H}}_{4}\mathrm{NHO}$. Here, a freezing of the ${\mathrm{PF}}_{6}$ rotation modes is revealed by several steplike increases of the temperature-dependent second spectral moment, with accompanying broad peaks of the longitudinal and transverse nuclear spin-relaxation rates. An analysis based on the Bloembergen-Purcell-Pound (BPP) theory quantifies the related activation energies as ${E}_{a}/{k}_{B}=250$ and 1400 K. Further, the anisotropy of the second spectral moment of the $^{31}\mathrm{P}$ absorption line was calculated for the rigid lattice, as well as in the presence of several sets of ${\mathrm{PF}}_{6}$ reorientation modes, and is in excellent agreement with the experimental data. Whereas the anisotropy of the frequency shift and enhancement of nuclear spin-relaxation rates is driven by the molecular rotation with respect to the dipole fields stemming from the Cu ions, the second spectral moment is determined by the intramolecular interaction of nuclear $^{19}\mathrm{F}$ and $^{31}\mathrm{P}$ moments in the presence of the distinct rotation modes.