Free-standing hybrid film for separation of dye pollutant with self-cleaning ability under visible light

Abstract

The development of low cost and environmental-friendly materials has long been an ambition for effective removal of dye pollutants in complex water environments. In this study, a free-standing separation film of bacterial cellulose reinforced/functionalized by graphitic phase carbon nitride is developed by a facile suction filtration strategy, of which the former is precoated by polypyrrole, and the latter is pre-doped by oxygen to endow the as-obtained film an enhanced photocatalytic performance and self-cleaning ability. The as-obtained film exhibits a high tensile stress of 51.8 ± 1.1 MPa, and a high resistance to cold, heat, acid and alkali. For typical dyes of methylene blue and rhodamine B, a high dye rejection rate of 99.9% at 138 L/m2•h•bar feed flux is obtained by the as-obtained film. Even at a salt concentration higher than 5%, it still maintained high dye removal rates and achieves effective separation of dye and salt. Simultaneously, a high dye photocatalytic degradation of the composite films rates up to 98% in only 90 min, and a high self-cleaning ability demonstrated by recovery of flux after light treatment in cyclic tests. The density functional theory calculation validates the beneficial effects of improved light response range and separated photogenerated electron/holes for the effective degradation of dyes by oxygen-doped carbon nitride coupled with one-dimensional polypyrrole chains. Overall, this study proposes a new direction for the separation of dye pollutants with a high visible-light self-cleaning capacity by structural tailoring of bacterial cellulose with carbon nitride.