Freestanding 3D mesoporous Co₃O₄@carbon foam nanostructures for ethanol gas sensing.

Abstract

Metal oxide materials have been widely used as gas-sensing platforms, and their sensing performances are largely dependent on the morphology and surface structure. Here, freestanding flower-like Co3O4 nanostructures supported on three-dimensional (3D) carbon foam (Co3O4@CF) were successfully synthesized by a facile and low-cost hydrothermal route and annealing procedure. The morphology and structure of the nanocomposites were studied by X-ray diffraction, X-ray photoelectron spectroscopy, energy-dispersive spectroscopy, and scanning electron microscopy (SEM). The SEM characterizations showed that the skeleton of the porous carbon foam was fully covered by flower-like Co3O4 nanostructures. Moreover, each Co3O4 nanoflower is composed of densely packed nanoneedles with a length of ~10 μm, which can largely enhance the surface area (about 286.117 m(2)/g) for ethanol sensing. Gas sensor based on the as-synthesized 3D Co3O4@CF nanostructures was fabricated to study the sensing performance for ethanol at a temperature range from 180 to 360 °C. Due to the 3D porous structure and the improvement in sensing surface/interface, the Co3O4@CF nanostructure exhibited enhanced sensing performance for ethanol detection with low resistance, fast response and recovery time, high sensitivity, and limit of detection as low as 15 ppm at 320 °C. The present study shows that such novel 3D metal oxide/carbon hybrid nanostructures are promising platforms for gas sensing.