Abstract
Abstract Although the ionic ring-opening polymerization of heterocyclic compounds, such as ethylene oxide, tetrahydrofuran, ethylen-imine, β-propiolactone, and caprolactam, as well as the Ziegler-Natta ring-opening of cyclic olefins, such as cyclopentene and norbornene, are well known, free radical ring-opening polymerizations are rather rare. The few examples that are reported in the literature involve cyclopropane derivatives or highly strained bi-cyclic olefins. For example, Takahashi [l] studied the free radical polymerization of vinylcyclopropane and reported that the cyclopropane ring opened to give a polymer containing about 80% 1,5-units and about 20% of undetermined structural units.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
More From: Journal of Macromolecular Science: Part A - Chemistry
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.