Abstract
The γ-nitrogen of phenylsulfonyl azide can be readily -labeled with 15 N by treating benzenesulfonyl hydrazide with Na 15 NO 2 . The resulting γ- 15 N-labeled sulfonyl azide reacts with carbon-centered free radicals to produce alkyl azides exclusively containing a C- 15 N bond. This chemistry provides valuable insight into the free-radical azidation mechanism as well as providing a mild method for the production of 15 N-amines.
Full Text 
Sign-in/Register to access full text options
Sign-in/Register to access full text options 
Published version (
Free)
Free) 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a call
