Abstract
A method to determine the relative rate of addition of methyl radicals to each end of a series of fluoroethylenes has been developed and the following differences (Δ) in activation parameters determined. CH3·+ RCHCH2[graphic omitted]CH3CH2ĊHR [graphic omitted] These figures show considerably different trends to those observed for the addition of trichloromethyl and heptafluoropropyl radicals to the same olefins.
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More From: Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases
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