Abstract
The methoxy free radical has been formed in a supersonic free jet expansion by KrF photolysis of methyl nitrite. Its laser-induced fluorescence excitation and wavelength-resolved emission spectra have been recorded at low temperature. This paper reports the vibronic analysis of the CH/sub 3/O and CD/sub 3/O /tilde A//sup 2/A/sub 1/ /leftrightarrow/ /tilde X//sup 2/E electronic spectra. A new value for the electronic origin has been determined as well as a nearly complete set of vibrational frequencies.
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