Abstract

We propose an approach to the description of orientational phase transitions that utilizes the specific features of orientational energy and entropy. The approach is applied to building a model for nematic phases in materials with nonpolar parallelepiped-type molecules with symmetry D(2h). The model operates with complex order parameters, generalizes the Landau-de Gennes theory, and predicts the existence of a biaxial nematic phase for the fourth-order expansion of free energy.

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