Abstract
The Helmholtz free energy and radial distribution functions were calculated for impurity and vacancy point defects in AgCl doped with 1–5 mole % CdCl2 at 250 °C. The model assumed a Coulombic interaction except at the nearest-neighbor separation. The method was a variational solution of the hypernetted chain integral equations. The relation of the calculation method and results to liquid electrolyte solution theory is discussed. The degree of association into nearest-neighbor vacancy–impurity complexes is not close to zero, contrary to recent suggestions. The results are consistent with the occurrence of triplet (and possibly larger) nearest-neighbor complexes in addition to the pairs.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
