Frank-Condon factors and absolute oscillator strengths for NH, SiH, S 2 and SO

Abstract

RKR Franck-Condon factors and r-centroids have been calculated for transitions of NH, SiH(SiD), S 2, and SO. Radiative lifetime data from this laboratory are used to derive absolute transition probabilities for the prominent transitions. The derived absolute transition probabilities are compared with literature values.