Abstract
The Franck-Condon factors and r-centroids, which are very closely related to relative vibrational tran- sition probabilities, have been computed by the more re- liable numerical integration procedure for the bands of A 2 X 2 r system of SiD, D 2+ X 2 r of SiF and D 2 i A 2 i system of SiN molecules of astrophysical in-
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