Abstract
A suitable potential energy function was found by analysing the potential functions proposed by Morse, Mohammad and Rafi et al. for the A2?+-X2?3/2 and B2?+-X2?3/2 band systems of GeF and the 1?-1? band system of SiF. It was found that the potential proposed by Rafi et al. is in close agreement with the Rydberg-Klein-Rees (R-K-R) potential. Using this potential, the wave functions were evaluated by the Wentzel-Kramer-Brillouin (W-K-B) method. The Franck-Condon factors and r-centroids were computed by a numerical integration technique. The results are compared with available theoretical values. The intensities of the various bands were investigated.
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