Fracture Micromechanisms of Polypropylene/Polycarbonate/Poly(styrene-b-(ethylene-co-butylene)-b-styrene) (PP/ PC/SEBS) Ternary Blends: The Effects of SEBS Content

Abstract

Ternary blends of polypropylene/polycarbonate/poly(styrene-b-(ethylene-co-butylene)-b-styrene) (PP/PC/SEBS) with varying SEBS contents were produced via melt blending in a co-rotating twin-screw extruder. The phase morphology of the resulting ternary blends and its relationship with bending and impact behaviors were studied. Transmission optical microscopy (TOM) of the crack tip damage zone and scanning electron microscopy (SEM) of impact fractured surfaces were performed to characterize the fracture mechanism. With increasing SEBS content in the PP/PC/SEBS ternary blends, the number of PC/SEBS core-shell particles increased and the size of the core-shell particles enlarged. It was shown that with an SEBS content of 5%, the crack initiation resistance decreased and then was almost unchanged with further increase of SEBS content, while resistance to crack growth increased continuously with increasing of SEBS content. Preliminary analysis of the micromechanical deformation suggested that the high impact toughness observed for samples containing 20 and 30 wt% of SEBS could be attributed to cavitation of the rubbery shell and, consequently, shear yielding of the matrix. This plastic deformation absorbed a tremendous amount of energy. Due to low interfacial adhesion between PC particles and PP matrix in samples containing 5 and 10 wt% of SEBS, debonding occurred too early, so the occurrence of matrix shear yielding was delayed and resulted in premature interfacial failure and, hence, rapid crack propagation.