Fractionation, sources and budgets of potential harmful elements in surface sediments of the East China Sea

Abstract

Total concentrations, chemical fractions by BCR procedure and enrichment factors of nine potential harmful elements (V, Cr, Co, Ni, Cu, Zn, Mo, Cd and Pb) in surface sediments of the East China Sea (ECS) were investigated. Spatial distributions illustrated that PHEs (potential harmful elements) were mainly from the Changjiang River and the Jiangsu coastal current, except Pb which was influenced by atmospheric input. Sediments in the ECS were moderately polluted with Cd, Pb, Zn and Cu according to their enrichment factors (EFs). Distributions of EFs and labile fractions revealed that anthropogenic Cd and Cu were mainly input though the Changjiang, Pb pollutant was delivered from the Changjiang and atmosphere, while Zn was impacted by terrestrial pollution from the Changjiang and the Hangzhou Bay. Budget calculation showed that the Changjiang contributed 82–90% of PHE influxes. Thirty-eight to 77% of PHEs were buried in sediment, mainly along the inner shelf.