Abstract

A sensitive and selective method is described for the determination of neodymium in mixed rare earths using fourth-derivative spectrophotometry. The method is based on the absorption spectra of 4f electron transitions of the complex of neodymium with methyl thymol blue and cetylpyridinium chloride. The influence of various instrumental parameters and reaction conditions for maximum colour development are investigated. The calibration curve is linear over the range 0–3.5 μg ml−1 neodymium. The relative standard deviation for determination of 1.4 μg ml−1 neodymium (n = 7) is 1.6%. The detection limit (signal-to-noise ratio = 3) is 0.2 μg ml−1.

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