Abstract
TheA2Σ+–X2Πinear-infrared electronic transition of AgO was observed for the first time. The spectrum was recorded with the high resolution Fourier transform spectrometer associated with the McMath–Pierce Solar Telescope at Kitt Peak. The excited AgO molecules were produced in a low pressure silver hollow cathode sputter source. Constants for theA2Σ+state of107AgO and109AgO and improvedX2Πiconstants for107AgO and109AgO are presented. These two states are not a unique perturber pair and they do not follow the pure precession model.
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