Fourier transform IR spectroscopy of protonated cadmium arachidate layers in different positions of a perdeuterated multilayer

Abstract

The grazing incidence reflection IR spectra of protonated cadmium arachidate monolayers and bilayers at different positions in a deuterated multilayer on a gold surface were studied. In this way the degree of disorder in a single layer can be determined qualitatively as a function of distance from the substrate surface. The characteristic ratios of the CH stretching band intensities are interpreted in terms of increased disorder or tilt of the first monolayer on the substrate and the uppermost layers of the stack.