Abstract
Summary: FT ICR spectrometry has been used for gas-phase studies of the interaction between singly-charged positive tungsten ions and hydrocarbons (alkanes C2-C9, alkenes C2-C6, and cycloalkanes C3-C6). It is shown that this interaction results mainly in dehydrogenation products. The number of H2 molecules eliminated depends upon the size and type of hydrocarbon and varies from 1 to 6. Significant amounts of C-C cleavage products have been found in the cases of cyclopropane and 2-methylpropene only.
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