Four novel ion-pair compounds consisting of 7,7,8,8-tetracyanoquinodimethane (TCNQ) radical: Syntheses, crystal structures and properties

Abstract

Four novel ion-pair compounds, [IBzmethylPy][TCNQ] ( 1), [IBzdimethylPy][TCNQ] ( 2), [BrBzdimethylPy][TCNQ] ( 3) and [CNBzdimethylPy][TCNQ] ( 4) where [IBzmethylPy]Br = 1-(4-iodobenzyl)-3-methylpyridinium bromide, [IBzdimethylPy]Br = 1-(4-iodobenzyl)-3,5-dimethylpyridinium bromide, [BrBzdimethylPy]Br = 1-(4-bromobenzyl)-3,5-dimethylpyridinium bromide and [CNBzdimethylPy]Br = 1-(4-cyanobenzyl)-3,5-dimethylpyridinium bromide, have been prepared and structurally characterized. The difference of substituent group of pyridine ring leads to exhibit different packing structures. Two neighboring cations of [IBzmethylPy] + overlap into a dimer via π–π stacking between benzene rings in compound 1, while the cation are connected by hydrogen bonds and van de Waals interactions to form a 3D supramolecular architecture containing 1D channels in 2– 4. A strong dimer of [(TCNQ) 2] 2− is formed, and the adjacent dimers slide to each other along the direction of the shorter molecular axis of TCNQ − in 1– 4. The typical magnetic characteristics in 1– 4 are: (1) strong AFM coupling interaction within a TCNQ stack leads to the χ M T values at room temperature much smaller than expected spin-only value; (2) temperature dependent magnetic coupling behavior causes the plot of χ M −1 m versus T deviate from linearity; (3) The temperature dependences of magnetic susceptibility show spin gap of singlet–triplet feature. The best simulations to susceptibility data in the range 1.8–300 K yielded the parameters Δ /k B = 1723 K and zJ′/k B = −11 K for 1; Δ/k B = 1689 K and zJ′/k B = −7 K for 2; Δ/k B = 1682 K and zJ′/k B = −6 K for 3; Δ/k B = 1684 K and zJ′/k B = −8 K for 4. The paramagnetic behavior of compounds 1– 4 is proven by their electron paramagnetic resonance spectra with the characteristic bands of the radicals at 2.0063, 2.0067, 2.0060, and 2.0064, respectively.