Four coordination polymers based on 5-(3,5-dicarboxybenzyloxy) isophthalic acid: Synthesis, structures, photocatalytic properties, fluorescence sensing and magnetic properties

Abstract

Four coordination polymers named [Co(L)0.5(bib)]n(1), Zn(H2L)(bib)]·2H2O}n(2), Cd(L)0.5(1,2-bimb)]n(3) and Zn(L)0.5(bib)]n(4) (H4L ​= ​5-(3,5-dicarboxybenzyloxy) isophthalic acid, bib ​= ​1,4-bis(1-imidazolyl)benzene, and 1,2-bimb ​= ​1,2-bis(1-imidazolylmethyl)benzene) were synthesized by solvothermal method and structurally characterized by means of single-crystal X-ray diffraction, infrared spectra and elemental analyses. Complex 1 crystallized in orthorhombic space group Pbcn had a 2-fold interpenetrated framework. Complex 2 showed a 4-fold interpenetrated framework. Complex 3 presented a 3-fold interpenetrated framework that crystallized in the triclinic system Pī space group. Complex 4 was a three-dimensional (3D) porous framework. Remarkably, the photocatalytic degradation experiments of complexes 1–4 on methylene blue (MB) indicated that these complexes 1–4 exhibited obvious degradation effect on MB. Moreover, the investigation of the luminescent properties of complexes 2–4 revealed that these complexes 2–4 could be served as a potential highly selective Fe3+ ion luminescent sensor. In addition, the magnetic analyses of complex 1 indicated that there was antiferromagnetic interaction between the Co (II) ions in complex 1.