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Abstract
AbstractFour‐component reaction of arynes derived from 2‐(trimethylsilyl)aryl triflates with primary amines and aldehydes, followed by the addition of chloroform or aromatic aldehydes in the presence of CsF was accomplished, featuring sequential formation of imines, nucleophilic addition, proton abstraction of chloroform or electrophilic addition of aromatic aldehydes, and intramolecular cyclization in one‐pot operation. The reactions proceed under mild conditions and have broad perspective for selecting starting substrates.
Published Version
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