Formulation of UV curable nano-silver conductive ink for direct screen-printing on common fabric substrates for wearable electronic applications

Abstract

One-step printing of electrically conductive inks on textiles is one of the simplest and most prospective methods to manufacture functional wearable electronics. However, the high surface roughness and porous structure as well as poor temperature endurance of most textiles have become the major challenges for the realization of printed electronic textiles (E-textiles). To solve these issues, the UV curable conductive ink with fast curing and low temperature characteristics was formulated to fabricate the flexible fabric-based conductive patterns using screen printing method. The specific focus was spent on investigating the effect of ink composition on curing speed, film forming ability, morphological characteristics and electrical properties of conductive patterns directly printed on fabric substrates. Firstly, we determined the necessity of defoamer for the formation of uniform and continuous printed textile-based patterns, and optimized the film forming ability of UV-curing ink by exploring the defoamer performance. Then, the ink curing speed was found heavily depending on the different types and contents of photoinitiators. Finally, the nano-silver loading showed critical influence to the screen-printability and the electrical properties of printed patterns. An ink formulation with 60 wt% nano-silver, 4 wt% photoinitiator (1173), and 0.2 wt% defoamer (BYK-555) showed satisfactory screen printability, and the conductive patterns with 1.0 mm width exhibited a remarkably low resistivity of 4.04 × 10−5 Ω cm. Moreover, the high performance of the conductive pattern screen-printed on four different fabrics by the formulated UV curable conductive ink further demonstrated its application potential. The results showed that uniformity and electrical properties of printed patterns were directlyrelated to the weaving method, texture characteristic, and roughness of thetextiles. We believe these results will provide basic guidance for the formulation design of conductive ink and facilitate the utility of textiles-based wearable electronics.