Abstract
AbstractThiazolium salt polymers synthesized by quaternization of 4‐(4′‐vinylphenyl)thiazole (VPT) polymers with methyl iodide had a highly catalytic activity for “the formose reaction.” Their catalytic activities were comparable to that of a low molecular weight analog, 3‐methyl‐4‐phenylthiazolium iodide (MPTI). In the reaction catalyzed by the polymer catalyst, a main product, dihydroxyacetone (DHA), was detected by gas‐liquid chromatography. The polymer catalysts were easily recovered from the reaction mixture and reused with a sustained catalytic activity. © 1992 John Wiley & Sons, Inc.
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