Abstract
Mixed transition metal oxides with favorable electrochemical properties are promising electrode materials in energy storage and conversion systems. In this work, uniform porous yolk-shell MnCo2O4 (denoted as YSM-MCO) microrugby balls have been synthesized by simple annealing treatment of metal carbonates with a microrugby ball shape in air. Benefiting from the desired porous structure and composition, the as-synthesized YSM-MCO exhibits enhanced electrochemical performance when investigated as anode materials for lithium-ion batteries and electrocatalysts for the oxygen evolution reaction. The YSM-MCO demonstrates remarkable lithium storage properties with a good cycling stability (94% capacity retention over 200 cycles at 0.5 A g-1) and superior rate capability (414 mA h g-1 at 5 A g-1). In addition, the YSM-MCO also exhibits better OER activity than most of the reported MnCo2O4-based electrocatalysts.
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