Abstract
Allyl hetaryl Sulfides with an allyl fragment that is part of a heteroaromatic ring undergo a [3,3]-sigmatropic rearrangement when they are heated in various solvents, as a result of which uncondensed binuclear heterocyclic compounds are formed. On the basis of kinetic data it was shown that the inclusion of the vinyl or allyl fragment of a sulfide in the composition of the heteroaromatic ring hinders the rearrangement more, the higher the aromatic character of the heteroring.
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