Abstract

The formation of the structure of titanium dioxide containing 3–15 wt % CeO2 in a wide temperature range (300–850°C) has been investigated by X-ray powder diffraction, electron microscopy, and adsorption methods. Modification of titanium dioxide with cerium oxide causes the formation of nanostructured Ce-Ti-O compounds consisting of incoherently intergrown fine anatase crystallites. The crystallites are separated by interblock boundaries in which cerium ions are stabilized. The nanostructure formed in the Ce-TiO2 oxide system stabilizes the anatase phase, prevents the sintering of anatase particles at high temperatures, and allows modified anatase to retain a larger specific surface area and a higher porosity upon heat treatment than pure titanium dioxide does.

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