Formation of Sediment-Hosted Opal-AG at Lightning Ridge (New South Wales, Australia): Refining the Deep Weathering Model

Abstract

Formation of sedimentary opal-AG in opal fields of eastern Australia has been linked to intensive weathering of their Cretaceous host rocks—the “deep weathering” model. Here we examine possible links between weathering history as recorded in mining exposures and textural observations in thousands of opal nodules from Lightning Ridge (New South Wales, Australia) to further constrain the timing and depositional environment of opal-AG. Satellite imaging identifies river channels—now marked by pedogenic silcrete—associated with an inland river delta as the intermittent source of water that drove localized deep weathering and silicification in reactive volcanogenic sediments. Variably mineralized weathering profiles show evidence for wet/dry cycling that controlled redox and pH fluctuations critical in the conversion of detrital feldspar to kaolinite, release of silica, formation of opaline silica spheres, and opal mineralization during the initial intense phase of weathering. Subsequent less intense weathering under consistently oxidizing conditions modified the weathering profiles but produced little further opal. Textures in oriented opal nodules indicate that cavities filled rapidly under changing Eh-pH. Opal nodules formed when opaline silica spheres, nucleated and grown in perched groundwater bodies, accumulated and drained into cracks and dissolution cavities in underlying claystone. Drier conditions promoted sol-gel ripening processes that produced the solid opal. Patches and bars of precious opal-AG within common opal nodules suggest that it formed through oxidation, diffusion, and leaching in common opaline Si gel during periods of low water flux and was rate limited by the solidification of the Si gel. Ostwald ripening increased silica sphere size to produce the characteristic “play of color.” Opal formation largely ceased once acidification potential was lost or all feldspar had been converted to kaolinite.