Abstract
The transient optical absorption bands ( λ max = 290, 475 nm) formed on the reactions of OH radicals in an acidic aqueous solution of chlorobenzene are assigned to the solute radical cation. It decays (475 nm) by first-order kinetics with k = 1.8 × 10 4s −1. The extinction coefficient (475 nm) is determined to be 7.87 × 10 3dm 3mol −1cm −1.
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