Abstract

Etude cinetique et mecanisme de formation d'isomeres des especes [(H 2 O)(en) 2 Rh(OH) Rh(en) 2 (OH)] 4+ et [(en) 2 Rh(OH) 2 Rh(en) 2 ] 4+ a partir de l'hydrolyse du complexe mononucleaire du titre, en=ethylenediamine. Etudes quantitatives au moyen de la chromatographie HPLC et de la spectrophotometrie. Constantes d'equilibre entre les isomeres racemiques, parametres thermodynamiques

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