Abstract

Abstract The reactions of carbonyl compounds with dimethyl trimethylsilylmethylphosphonate gave terminal olefins, dimethyl methylphosphonate, methyl trimethylsilyl methylphosphonate, and dimethyl trimethylsilyl phosphate. Terminal olefins may be formed by a Wittig type reaction of carbonyl compounds with a phosphorus ylide produced via 1,3-silyl migration of dimethyl trimethylsilylmethylphosphonate.

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