Abstract
Stepwise, low-temperature reaction of {Pd[CH(SiMe3)2](PMe3)(μ-Cl)}2 with CNBu-t and NaCp‘ (Cp‘ = C5H5, C5H4Me) affords metal-substituted fulvenes of composition {Pd[C(NHBu-t)C(C4H3R)][CH(SiMe3)2](CNBu-t)(PMe3)}, of which the C5H4Me-derived complex 2b (R = Me) has been characterized by X-ray crystallography. The formation of related complexes of Pt is also reported.
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