Abstract

The formation of interfaces between the single-crystalline InAs(001) surface and organic semiconductor molecules (PTCDA and NTCDA) is investigated. With the methods of total current spectroscopy and Auger electron spectroscopy, it is found that indium atoms diffuse from the substrate into the molecular film. Indium atoms present in the film change the structure of its π-electron states and decrease the energy of unoccupied molecular orbitals.

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