Abstract
Amphiphilic block copolymer EO20PO70EO20 (Mn = 5800 g/mol) has been modified with terpyridine (tpy) end groups as a building block for the construction of metallosupramolecular polymers. The synthesized tpy-terminated EO20PO70EO20 1 assembles into a linear supramolecular polymer by a metal−ligand interaction between two tpy terminates of 1 and one iron ion. Use of EO20PO70EO20 having tpy terminates 1 as a template for the sol−gel polymerization of tetraethoxysilane (TEOS) results in the preparation of well-ordered hexagonal mesoporous silica structure, in which 1 is filled within highly ordered mesoporous silica channels. The incorporated tpy-terminated copolymers assemble into metallosupramolecular polymers by the formation of metal complexes within the silica mesochannels.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
