Abstract
The construction of supramolecular structures by simple cocrystallization of compounds whose molecular building blocks are complementary is amazingly easy. Td-symmetric molecules that can function as Hbond donors, for instance [{M(CO)3(μ3OH)}4] (M MnI, ReI) (shown on the right), and bi- or multifunctional Hbond acceptors such as 1,3-diaminopropane and hexamethylenetetramine form two-dimensional “chickenwire” networks.
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More From: Angewandte Chemie International Edition in English
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