Abstract

The formation of cluster ions when hydrogen molecular ions H 2 + and H 3 + are injected into a drift tube filled with helium gas at 4.4 K has been investigated. When H 2 + ions are injected, cluster ions HHe x + (x≦14) are produced. No production of H2He x + ions is observed. When H 3 + ions are injected, cluster ions HHe x + (x≦14) are produced as well as H3He x + (x≦13), and very small signals corresponding to H2He x + (3≦x≦10) are observed. Information on the stability of HHe x + and H3He x + is derived from the drift field dependence of the cluster size distributions. The cluster sizex=13 is found to be a magic number for HHe x + , and for H3He x + ,x=10 and 11.

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