Abstract
IT has recently been shown1 that the reaction of hydrated electrons, illustration, with hydronium ions, illustration, does not yield H-atoms but H3O radicals. It therefore seemed possible that H3O radicals could decay to yield H atoms. If this is the case, the reactivity of the species produced by the reaction illustration+illustration should be a function of the solute concentration. To test this hypothesis I studied the effect of the concentration of nitrobenzene, C6H5NO2, on the second order rate constant for the formation of nitro-cyclohexadienyl radicals, HC6H5NO2, from species produced by the reaction of illustration with illustration Open image in new window Open image in new window
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