Abstract
Exotic atoms like muonic atoms can be formed either by direct capture, often called Coulomb capture, or by muon transfer from a muonic hydrogen atom. The first estimates for the formation predicted, for both mechanisms, probabilities approximately proportional to the charge numberZ. The experiments did not confirm such a simpleZ-dependence. In direct capture, it turned out that the chemical bond played a decisive role, at least for lighter elements. In the formation via transfer, surprising data were obtained not only for heteroatomic molecules but also for noble gases. Whereas for direct capture, a model is able to reproduce quite satisfactorily a great number of measured capture ratios, including those in hydrogen compounds, the formation via transfer seems to put completely different and more fundamental questions.
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