Abstract
Thiophene selectively binds to the pair of adjacent Si adatom and Si rest atom on the Si(111)-(7×7) surface, leading to the covalent attachment of C–S–C linkages onto the surface. Cu atoms are found to preferentially adsorb onto the S atoms of the functional C–S–C groups in the formation of copper nanoclusters on the thiophene-mediated Si(111)-(7×7) surface.
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